三维电极电化学反应器深度处理焦化废水

为探索焦化废水深度处理新途径,采用了焦粒、活性炭负载Mn（NO3）2和Zn（NO3）2化合物粒子电极为第3极的三维电极反应器对二级生化处理后的焦化废水进行深度处理。考察了焦化废水中有机物去除的影响因素及处理效果,并探讨了有机物的降解动力学。结果表明,以焦粒为载体的粒子电极三维电极系统在pH为6.5,电导率为4 580μS/cm,电流密度为16 mA/cm2,投加量大于25 g/L时,降解20 min,COD去除率超过35%以上。焦化废水的降解的动力学研究表明,焦化废水降解符合表观一级反应动力学规律。该研究可为三维电极反应器在焦化废水深度处理工程应用中提供参数依据。     

A study of the atmospheric dispersion of a high release of krypton-85 above a complex coastal terrain, comparison with the predictions of Gaussian models (Briggs, Doury, ADMS4)

Atmospheric releases of krypton-85, from the nuclear fuel reprocessing plant at the AREVA NC facility at La Hague (France), were used to test Gaussian models of dispersion. In 2001-2002, the French Institute for Radiological Protection and Nuclear Safety (IRSN) studied the atmospheric dispersion of 15 releases, using krypton-85 as a tracer for plumes emitted from two 100-m-high stacks. Krypton-85 is a chemically inert radionuclide. Krypton-85 air concentration measurements were performed on the ground in the downwind direction, at distances between 0.36 and 3.3 km from the release, by neutral or slightly unstable atmospheric conditions. The standard deviation for the horizontal dispersion of the plume and the Atmospheric Transfer Coefficient (ATC) were determined from these measurements. The experimental results were compared with calculations using first generation (Doury, Briggs) and second generation (ADMS 4.0) Gaussian models. The ADMS 4.0 model was used in two configurations; one takes account of the effect of the built-up area, and the other the effect of the roughness of the surface on the plume dispersion. Only the Briggs model correctly reproduced the measured values for the width of the plume, whereas the ADMS 4.0 model overestimated it and the Doury model underestimated it. The agreement of the models with measured values of the ATC varied according to distance from the release point. For distances less than 2 km from the release point, the ADMS 4.0 model achieved the best agreement between model and measurement; beyond this distance, the best agreement was achieved by the Briggs and Doury models.     

基于虚拟现实技术的喷射火事故三维动态仿真及应用

基于Shell模型的原理和计算方法,把喷射火焰视为近似倒立圆台形,构建了不同风向影响下的喷射火三维模型,运用虚拟现实技术和三维可视化技术对喷射火事故进行模拟与仿真。以Delphi和OpenGL/GLScene为开发工具,实现了喷射火三维模型的程序化与三维场景绘制,同时引入粒子特效系统,实现了喷射火焰燃烧的实时动态仿真,完成了喷射火三维动态可视化软件系统的开发。最后,利用该系统进行实例分析。应用表明:虚拟现实技术与事故后果模拟相结合,使整个系统实现实时性和形象性的统一,虚拟现实技术在化工行业具有广泛应用前景,也为事故后果预测评估提供科学依据。     

复杂地形对含硫气井应急计划区划分的影响

研究复杂地形对含硫气井应急计划区(EPZ)划分的影响,为高风险油气田的安全生产提供参考。根据含硫气井井口与周边地形的关系,将复杂地形分为3类;选择不同类型复杂地形的3口含硫气井,采用大涡模拟方法模拟不同H2S释放速率、不同风速和风向、不同井喷点火时间的组合条件下H2S大气扩散质量浓度场,积分计算各井H2S毒性负荷的时空分布。在此基础上,研究EPZ半径与H2S释放速率之间的关系,然后建立以H2S释放速率为指标的不同类型复杂地形含硫气井EPZ的划分方法。结果表明第一类模型计算结果明显大于第二类和第三类模型,第三类模型的计算结果最小,此差异随着H2S释放速率增大而愈显著。计算结果合理,方法适用且可行。     

活性炭三维电极流化床处理洗车废水的研究

以经吸附处理的活性炭为填充粒子，对三维电极流化床反应器处理洗车废水进行了静态条件实验研究。结果表明：三维电极流化床处理洗车废水的效果明显好于三维电极固定床和单纯的活性炭吸附。在槽电压为30 V，通气量为3 L/min， 通电时间为30 min，活性炭用量为50 g时，COD去除率最高。     

钢线拉丝及表面处理生产线成套装备

主要论述了一种钢线拉丝及表面处理生产线成套装备的设计。该生产线的生产方式是多根钢线在牵引动力系统的作用下依次穿过各种处理设备,完成各道工序,实现钢线完成表面处理的目的。这个生产过程中,钢线可以完成放线、脱脂、退火、镀镍、造膜、烘干及收线一体化的工序。采用立体式布置,空间利用更为合理。     

Computational Fluid Dynamics (CFD) Simulations on the Effect of Rough Surface on Atmospheric Turbulence Flow Above Hilly Terrain Shapes

The behavioral distribution of the atmospheric turbulence flow over the terrain with changes in a rough surface has become one of the most important topics of air pollution research, among such other topics as transportation and dispersion pollutants. In this study, a computational model on atmospheric turbulence flow over a terrain hill shaped with rough surface was investigated under neutral atmospheric conditions. The flow was assumed to be 2D and modeled using computational fluid dynamics (CFD) models, which were numerically solved using Reynolds-averaged Navier-Stokes equations. Rough surface conditions were modeled using a number of windbreak fences regularly spaced on the hill. The mean velocity and turbulent structures such as turbulence intensity and turbulent kinetic energy were investigated in the upwind and downwind regions over the hill, and the numerical models were validated against the wind-tunnel results to optimize the turbulence model. The computational results agreed well with the results obtained from the wind tunnel experiments. The computational results indicate that the mean velocity was observed to increase dramatically around the crest of the upwind slope of the hill. A thick internal boundary layer was observed with a fence on the crest and downwind region of the hill. The reversed flow and recirculation zone were formed in the wake region behind the hill. It was thus determined that turbulent kinetic energy decreases as the mean velocity increases.     

构建三元混合污染物的三维等效图

等效线分析法广泛应用于二元混合物的毒性相互作用评估.然而,如何构建三维等效图以考察三元混合物中发生的毒性相互作用至今没有文献报道.本研究的主要目的即以三元混合物中3个组分的相对浓度为坐标轴建立三维等效图以考察三元混合物的毒性相互作用.以6种目前在中国广泛使用的农药,包括3种除草剂(2,4-D、敌草净、西草净)和3种杀虫剂(乐果、吡虫啉、残杀威)为混合物组分,采用均匀设计射线法(UD-Ray)分别对三元除草剂和三元杀虫剂混合物中各组分浓度分布进行优化设计,以全面表征实际混合物的浓度多样性.通过费氏弧菌微板毒性分析法测定农药及其三元混合物在不同浓度下的发光抑制毒性,以浓度加和(CA)模型为加和参考模型,建立三维等效图,分析各混合物的毒性相互作用.结果表明,三维等效图能清晰、直观地反映三元混合物的毒性相互作用信息,开拓等效分析法在三元混合物毒性分析中的应用.     

乌江水库水体中有机胶粒的三维荧光特征研究

超滤与三维荧光光谱的结合可以表征不同类型荧光物质相对分子量的分布规律,揭示它们的来源以及组分差异.本项研究用截留相对分子量为1 000和10 000的再生纤维素超滤膜,对乌江水库不同深度水体中的溶解有机质进行了分离,利用三维荧光光谱表征了3种不同相对分子量组分中发荧光有机质的光谱特征.结果表明:荧光物质主要存在于真溶液(＜1 000)中.水体在丰水期和枯水期的荧光峰存在差异.丰水期主要存在4种类型的荧光峰:类富里酸荧光A峰和C峰,类蛋白荧光峰B峰和D峰.枯水期则只表现出3种类型的荧光峰,类富里酸荧光峰C不明显,原因可能是此时水库处于蓄水状态,内部生物活动作用显著,产生的类蛋白荧光物质强度较大从而掩盖峰C的强度.然而72 m以下由于厌氧还原条件的出现,沉积物向水体释放了溶解有机质组分,原本强度被掩盖的荧光峰C明显出现在1 000～10 000组分中.     

可靠性鉴定试验受试样品的软硬件联合测试技术

为了研究一种可靠性鉴定试验中受试样品的软硬件联合测试方法,首先总结了软硬件联合测试的目的、对象、实施时机及传统测试需要的改进之处和可借鉴之处,进一步研究了软硬件联合测试与传统可靠性试验的关系。然后在考查软件与硬件测试结合的基础上,提出了两层结构立体测试运行剖面的方法,即利用子剖面与环境剖面的对应关系建立软件测试与硬件测试的联系,将两种测试统一在同一时间轴上,得出了软硬件联合测试的一般流程。